Birman Vladimir B, Li Ximin
Department of Chemistry, Washington University, Campus Box 1134, One Brookings Drive, St. Louis, MO 63130, USA.
Org Lett. 2008 Mar 20;10(6):1115-8. doi: 10.1021/ol703119n. Epub 2008 Feb 16.
Homobenzotetramisole (HBTM), a ring-expanded analogue of the previously reported catalyst BTM, displays higher catalytic activity and a different structure-selectivity profile. It displays good enantioselectivities in kinetic resolution of secondary benzylic alcohols but is particularly effective for 2-aryl-substituted cycloalkanols.
高同苯并四咪唑（HBTM）是先前报道的催化剂BTM的扩环类似物，具有更高的催化活性和不同的结构选择性特征。它在仲苄醇的动力学拆分中表现出良好的对映选择性，尤其对2-芳基取代的环烷醇有效。
