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2
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本文引用的文献

1
Effects of Methyl Substituents on the Activity and Enantioselectivity of Homobenzotetramisole-Based Catalysts in the Kinetic Resolution of Alcohols.甲基取代基对基于均苯并四咪唑的催化剂在醇的动力学拆分中的活性和对映选择性的影响。
Adv Synth Catal. 2009 Oct 1;351(14-15):2525-2529. doi: 10.1002/adsc.200900383.
2
Homobenzotetramisole-Catalyzed Kinetic Resolution of alpha-Aryl-, alpha-Aryloxy-, and alpha-Arylthioalkanoic Acids.均苯并四咪唑催化的α-芳基、α-芳氧基和α-芳硫基链烷酸的动力学拆分
Adv Synth Catal. 2009;351(14):2301-2304. doi: 10.1002/adsc.200900451.
3
Organocatalytic asymmetric addition of alcohols and thiols to activated electrophiles: efficient dynamic kinetic resolution and desymmetrization protocols.醇和硫醇对活化亲电试剂的有机催化不对称加成：高效的动态动力学拆分和去对称化方法
J Org Chem. 2008 Aug 15;73(16):6409-12. doi: 10.1021/jo801158g. Epub 2008 Jul 23.
4
Homobenzotetramisole: an effective catalyst for kinetic resolution of aryl-cycloalkanols.均苯并四咪唑：一种用于芳基环烷醇动力学拆分的有效催化剂。
Org Lett. 2008 Mar 20;10(6):1115-8. doi: 10.1021/ol703119n. Epub 2008 Feb 16.
5
The diverse chemistry of oxazol-5-(4H)-ones.恶唑-5-(4H)-酮的多样化学性质。
Chem Soc Rev. 2007 Sep;36(9):1432-40. doi: 10.1039/b511113g. Epub 2007 Mar 12.
6
Structural optimization of thiourea-based bifunctional organocatalysts for the highly enantioselective dynamic kinetic resolution of azlactones.基于硫脲的双功能有机催化剂用于乙内酰脲高度对映选择性动态动力学拆分的结构优化
Org Biomol Chem. 2006 Dec 7;4(23):4319-30. doi: 10.1039/b607574f. Epub 2006 Nov 1.
7
Kinetic resolution of propargylic alcohols catalyzed by benzotetramisole.苯并四咪唑催化的炔丙醇的动力学拆分
Org Lett. 2006 Oct 12;8(21):4859-61. doi: 10.1021/ol061906y.
8
Kinetic resolution of 2-oxazolidinones via catalytic, enantioselective N-acylation.通过催化对映选择性N-酰化实现2-恶唑烷酮的动力学拆分
J Am Chem Soc. 2006 May 24;128(20):6536-7. doi: 10.1021/ja061560m.
9
Asymmetric synthesis of protected arylglycines by rhodium-catalyzed addition of arylboronic acids to N-tert-butanesulfinyl imino esters.通过铑催化芳基硼酸加成到N-叔丁基亚磺酰亚胺酯上实现受保护芳基甘氨酸的不对称合成。
J Am Chem Soc. 2006 May 17;128(19):6304-5. doi: 10.1021/ja060529h.
10
Benzotetramisole: a remarkably enantioselective acyl transfer catalyst.苯并四咪唑：一种具有显著对映选择性的酰基转移催化剂。
Org Lett. 2006 Mar 30;8(7):1351-4. doi: 10.1021/ol060065s.

苯并四咪唑催化的氮丙啶酮的动态动力学拆分。

Benzotetramisole-catalyzed dynamic kinetic resolution of azlactones.

机构信息

Department of Chemistry, Washington University, Campus Box 1134, One Brookings Drive, St. Louis, Missouri 63130, USA.

出版信息

Org Lett. 2010 Feb 19;12(4):892-5. doi: 10.1021/ol902969j.

DOI:10.1021/ol902969j
PMID:20099896
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3947837/
Abstract

Enantioselective acyl transfer catalyst benzotetramisole (BTM) has been found to promote dynamic kinetic resolution of azlactones providing di(1-naphthyl)methyl esters of alpha-amino acids with up to 96% ee.

摘要

手性酰基转移催化剂苯并四咪唑 (BTM) 已被发现可促进氮杂环丙烷酮的动态动力学拆分，得到的α-氨基酸的二(1-萘基)甲酯对映体过量值高达 96%。