Cao Hong, McNamee Laura, Alper Howard
Centre for Catalysis Research and Innovation, Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Ontario K1N 6N5, Canada.
J Org Chem. 2008 May 2;73(9):3530-4. doi: 10.1021/jo800287s. Epub 2008 Apr 3.
Trihexyl(tetradecyl)phosphonium hexafluorophosphate, a phosphonium salt ionic liquid (PSIL) is a particularly effective general reaction media for the Pd-catalyzed carbonylation reaction of iodoarenes and thiols to form thioesters. Recycling of the ionic liquid containing active Pd-catalyst was also demonstrated.
三己基（十四烷基）鏻六氟磷酸盐，一种鏻盐离子液体（PSIL），是用于碘代芳烃与硫醇的钯催化羰基化反应以形成硫酯的特别有效的通用反应介质。还展示了含活性钯催化剂的离子液体的循环利用。
