通过使用三原子配体作为桥梁构建磁性分子固体。
Constructing magnetic molecular solids by employing three-atom ligands as bridges.
作者信息
Wang Xin-Yi, Wang Zhe-Ming, Gao Song
机构信息
Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
出版信息
Chem Commun (Camb). 2008 Jan 21(3):281-94. doi: 10.1039/b708122g.
The combination of some three-atom bridges with paramagnetic 3d transition metal ions results in the systematic isolation of molecular magnetic materials, ranging from single-molecule and single-chain magnets to layered weak ferromagnets and three-dimensional porous magnets. The design strategy and role of secondary components, such as co-ligands, templates and other mixed short ligands are discussed.
一些三原子桥与顺磁性3d过渡金属离子的结合，导致了分子磁性材料的系统分离，范围从单分子磁体和单链磁体到层状弱铁磁体和三维多孔磁体。文中讨论了辅助成分的设计策略和作用，如共配体、模板和其他混合短配体。
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