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来自海洋红藻三叉劳伦氏藻(红叶藻科)的月桂烷型倍半萜。

Laurane-derived sesquiterpenes from the marine red alga Laurencia tristicha (Rhodomelaceae).

作者信息

Ji N-Y, Li X-M, Li K, Ding L-P, Wang B-G

机构信息

Key Laboratory of Experimental Marine Biology, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, People's Republic of China.

出版信息

Nat Prod Res. 2008 May 20;22(8):715-8. doi: 10.1080/14786410802019309.

Abstract

Two new stereoisomers of laurane-derived brominated sesquiterpenes, 4-bromolaur-11-en-1,10alpha-diol (1) and 4-bromolaur-11-en-1,10beta-diol (2), one new natural product, laur-11-en-1,10alpha-diol (3), together with 11 known compounds (4-14) were isolated and identified from the organic extract of the marine red alga Laurencia tristicha. Their structures and relative stereochemistry were established by analysis of mass and NMR spectroscopic techniques.

摘要

从海洋红藻三叉劳伦氏藻的有机提取物中分离并鉴定出两种新的月桂烷衍生溴化倍半萜立体异构体,4-溴月桂-11-烯-1,10α-二醇(1)和4-溴月桂-11-烯-1,10β-二醇(2),一种新的天然产物月桂-11-烯-1,10α-二醇(3),以及11种已知化合物(4-14)。通过质谱和核磁共振光谱技术分析确定了它们的结构和相对立体化学。

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