Ma Zhongze, Lee David Y W
Bio-Organic and Natural Products Laboratory, McLean Hospital, Harvard Medical School, 115 Mill Street, Belmont, MA 02478.
Tetrahedron Lett. 2007 Jul 30;48(31):5461-5464. doi: 10.1016/j.tetlet.2007.05.179.
In comparison with the NMR data of salvinorin A and its 8-epimer, the published structure of deacetyl-1,10-didehydrosalvinorin G was revised to its 8-epimer. The stereochemistry of 8-epi-deacetyl-1,10-didehydrosalvinorin G was further confirmed by NOESY and chemical synthesis.
与Salvinorin A及其8-差向异构体的核磁共振数据相比，已发表的去乙酰基-1,10-二脱氢Salvinorin G的结构被修正为其8-差向异构体。通过NOESY和化学合成进一步证实了8-表-去乙酰基-1,10-二脱氢Salvinorin G的立体化学。
