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来自鸡蛋花(Plumeria rubra L. cv. acutifolia)花朵的两种新环烯醚萜非对映异构体的完整核磁共振光谱归属

Complete NMR spectral assignments of two new iridoid diastereoisomers from the flowers of Plumeria rubra L. cv. acutifolia.

作者信息

Ye Guan, Yang Yan-ling, Xia Guang-xin, Fan Ming-song, Huang Cheng-gang

机构信息

Shanghai Institute of Materia Medica, Shanghai Institutes for Biological Sciences, Chinese Academy of Sciences, Shanghai 201203, PR China.

出版信息

Magn Reson Chem. 2008 Dec;46(12):1195-7. doi: 10.1002/mrc.2331.

Abstract

Two new iridoid diastereoisomers (1, 2), together with five known compounds, were isolated from the flowers of Plumerian rubra L. cv. acutifolia. Their structures were elucidated by the means of in-depth spectroscopic and mass-spectrometric analyses, particularly 1D and 2D NMR spectroscopy.

摘要

从鸡蛋花的花朵中分离出两种新的环烯醚萜非对映异构体(1, 2)以及五种已知化合物。通过深入的光谱分析和质谱分析手段,特别是一维和二维核磁共振光谱,阐明了它们的结构。

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