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铑（I）催化的吡啶和喹啉的直接芳基化反应。

Rh(I)-catalyzed direct arylation of pyridines and quinolines.

作者信息

Berman Ashley M, Lewis Jared C, Bergman Robert G, Ellman Jonathan A

机构信息

Department of Chemistry, University of California, Berkeley, California 94720, USA.

出版信息

J Am Chem Soc. 2008 Nov 12;130(45):14926-7. doi: 10.1021/ja8059396. Epub 2008 Oct 15.

DOI:10.1021/ja8059396
PMID:18855360
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2647742/
Abstract

A Rh(I)-catalyzed direct arylation of pyridine and quinoline heterocycles has been developed. The method provides rapid entry into an important class of substituted heterocycles employing inexpensive and readily available starting materials.

摘要

已开发出一种铑（I）催化的吡啶和喹啉杂环的直接芳基化反应。该方法使用廉价且易于获得的起始原料，能够快速合成一类重要的取代杂环化合物。

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J Am Chem Soc. 2008 Jul 23;130(29):9254-6. doi: 10.1021/ja8026295. Epub 2008 Jun 27.
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Rhodium-catalyzed regioselective C-H functionalization via decarbonylation of acid chlorides and C-H bond activation under phosphine-free conditions.铑催化的通过酰氯脱羰作用和在无膦条件下的C-H键活化实现的区域选择性C-H官能化反应。
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Rh(I)-catalyzed arylation of heterocycles via C-H bond activation: expanded scope through mechanistic insight.通过C-H键活化实现铑（I）催化的杂环芳基化：基于机理洞察拓展反应范围
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