4-（吡啶-2-基）噻唑-2-基硫代糖苷作为通过暂时失活进行寡糖合成的双齿配体。
4-(pyridin-2-yl)thiazol-2-yl thioglycosides as bidentate ligands for oligosaccharide synthesis via temporary deactivation.
作者信息
Pornsuriyasak Papapida, Rath Nigam P, Demchenko Alexei V
机构信息
Department of Chemistry and Biochemistry, University of Missouri-St. Louis, St. Louis, Missouri 63121, USA.
出版信息
Chem Commun (Camb). 2008 Nov 21(43):5633-5. doi: 10.1039/b810569c. Epub 2008 Oct 1.
Abstract
This study focusses on a new concept for oligosaccharide synthesis based on 4-(pyridin-2-yl)thiazol-2-yl thioglycosides that can either act as effective glycosyl donors or can be deactivated by stable bidentate complexation with palladium(II) bromide.
摘要
本研究聚焦于基于4-(吡啶-2-基)噻唑-2-基硫代糖苷的寡糖合成新概念，该硫代糖苷既可以作为有效的糖基供体，也可以通过与溴化钯(II)形成稳定的双齿络合物而失活。
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