E Weinan, Vanden-Eijnden Eric
Department of Mathematics and Program in Applied and Computational Mathematics, Princeton University, Princeton, New Jersey 08544, USA.
Annu Rev Phys Chem. 2010;61:391-420. doi: 10.1146/annurev.physchem.040808.090412.
Transition-path theory is a theoretical framework for describing rare events in complex systems. It can also be used as a starting point for developing efficient numerical algorithms for analyzing such rare events. Here we review the basic components of transition-path theory and path-finding algorithms. We also discuss connections with the classical transition-state theory.
过渡路径理论是一种用于描述复杂系统中稀有事件的理论框架。它也可作为开发用于分析此类稀有事件的高效数值算法的起点。在此,我们回顾过渡路径理论和路径寻找算法的基本组成部分。我们还将讨论与经典过渡态理论的联系。