Kaufmann Patrik R, Federer Urs, Hutterli Manuel A, Bigler Matthias, Schüpbach Simon, Ruth Urs, Schmitt Jochen, Stocker Thomas F
Climate and Environmental Physics, Physics Institute, University of Bern, Bern, Switzerland.
Environ Sci Technol. 2008 Nov 1;42(21):8044-50. doi: 10.1021/es8007722.
Continuous flow analysis (CFA) is a well-established method to obtain information about impurity contents in ice cores as indicators of past changes in the climate system. A section of an ice core is continuously melted on a melter head supplying a sample water flow which is analyzed online. This provides high depth and time resolution of the ice core records and very efficient sample decontamination as only the inner part of the ice sample is analyzed. Here we present an improved CFA system which has been totally redesigned in view of a significantly enhanced overall efficiency and flexibility, signal quality, compactness, and ease of use. These are critical requirements especially for operations of CFA during field campaigns, e.g., in Antarctica or Greenland. Furthermore, a novel deviceto measure the total air content in the ice was developed. Subsequently, the air bubbles are now extracted continuously from the sample water flow for subsequent gas measurements.
连续流分析(CFA)是一种成熟的方法,用于获取冰芯中杂质含量的信息,作为气候系统过去变化的指标。冰芯的一段在提供样品水流的熔化头上连续熔化,该水流在线进行分析。这提供了冰芯记录的高深度和时间分辨率,以及非常高效的样品净化,因为只分析冰样的内部部分。在此,我们展示了一种改进的CFA系统,该系统鉴于显著提高的整体效率和灵活性、信号质量、紧凑性和易用性而进行了全面重新设计。这些是至关重要的要求,特别是对于在野外考察期间(例如在南极洲或格陵兰岛)进行CFA操作而言。此外,还开发了一种用于测量冰中总空气含量的新型装置。随后,现在从样品水流中连续提取气泡,用于后续的气体测量。