Furukawa Shuhei, Hirai Kenji, Nakagawa Keiji, Takashima Yohei, Matsuda Ryotaro, Tsuruoka Takaaki, Kondo Mio, Haruki Rie, Tanaka Daisuke, Sakamoto Hirotoshi, Shimomura Satoru, Sakata Osami, Kitagawa Susumu
ERATO Kitagawa Integrated Pores Project (Japan), Kyoto Research Park Bldg #3, Shimogyo-ku, Kyoto 600-8815, Japan.
Angew Chem Int Ed Engl. 2009;48(10):1766-70. doi: 10.1002/anie.200804836.
MOF on MOF: Core-shell porous coordination polymer (PCP) crystals are fabricated at the single-crystal level by epitaxial growth in solution. Synchrotron X-ray diffraction measurements unveiled the structural relationship between the shell crystal and the core crystal, where in-plane rotational epitaxial growth compensates the difference in lattice constant.
通过溶液中的外延生长在单晶水平上制备核壳多孔配位聚合物（PCP）晶体。同步加速器X射线衍射测量揭示了壳层晶体与核晶体之间的结构关系，其中面内旋转外延生长补偿了晶格常数的差异。
