韦利司他汀模型系列中的桥头烯醇盐和桥头烯烃。
Bridgehead enolates and bridgehead alkenes in a welwistatin model series.
作者信息
Boissel Valerie, Simpkins Nigel S, Bhalay Gurdip, Blake Alexander J, Lewis William
机构信息
School of Chemistry, The University of Nottingham, University Park, Nottingham, UK NG7 2RD.
出版信息
Chem Commun (Camb). 2009 Mar 21(11):1398-400. doi: 10.1039/b820674k. Epub 2009 Jan 21.
DOI:10.1039/b820674k
PMID:19259600
Abstract
Bridgehead metallation is possible in a ketone having the welwistatin skeleton, and this facilitates installation of the isothiocyanate function present in the natural product, and also enables synthesis of remarkable bridgehead alkenes.
摘要
在具有威斯塔汀骨架的酮中，桥头金属化是可能的，这有利于天然产物中异硫氰酸酯官能团的引入，并且还能够合成引人注目的桥头烯烃。
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