Wrenn B A, Virkus A, Mukherjee B, Venosa A D
Department of Energy, Environmental, and Chemical Engineering, Washington University, St. Louis, MO 63130, USA.
Environ Pollut. 2009 Jun;157(6):1807-14. doi: 10.1016/j.envpol.2009.01.025. Epub 2009 Mar 6.
The effects of surfactant composition on the ability of chemical dispersants to disperse crude oil in fresh water were investigated. The objective of this research was to determine whether effective fresh water dispersants can be designed in case this technology is ever considered for use in fresh water environments. Previous studies on the chemical dispersion of crude oil in fresh water neither identified the dispersants that were investigated nor described the chemistry of the surfactants used. This information is necessary for developing a more fundamental understanding of chemical dispersion of crude oil at low salinity. Therefore, we evaluated the relationship between surfactant chemistry and dispersion effectiveness. We found that dispersants can be designed to drive an oil slick into the freshwater column with the same efficiency as in salt water as long as the hydrophilic-lipophilic balance is optimum.
研究了表面活性剂组成对化学分散剂在淡水中分散原油能力的影响。本研究的目的是确定在考虑将该技术用于淡水环境时,是否能够设计出有效的淡水分散剂。以往关于原油在淡水中化学分散的研究既未明确所研究的分散剂,也未描述所用表面活性剂的化学性质。这些信息对于更深入地理解低盐度下原油的化学分散至关重要。因此,我们评估了表面活性剂化学性质与分散效果之间的关系。我们发现,只要亲水亲油平衡处于最佳状态,就可以设计出分散剂,使其将浮油驱入淡水水柱的效率与在盐水中相同。