Hasan Warefta, Stender Christopher L, Lee Min Hyung, Nehl Colleen L, Lee Jeunghoon
Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208-3113, USA.
Nano Lett. 2009 Apr;9(4):1555-8. doi: 10.1021/nl803647n.
This paper investigates how structural features of noble metal nanoparticles affect their photothermal properties. Using PEEL, we fabricated a range of Au nanopyramid-like particles with surface plasmon resonances tunable from visible to near-infrared wavelengths. By systematically varying geometric parameters including size, shell thickness, and presence or absence of tips, we determined which factors were most important in heat generation. For solutions with the same Au content, we discovered that pyramidal particles with thin shells and having sharp tips showed the largest photothermal response.
本文研究了贵金属纳米颗粒的结构特征如何影响其光热性质。利用等离子体增强电子能量损失谱(PEEL),我们制备了一系列表面等离子体共振可在可见光到近红外波长范围内调谐的金纳米金字塔状颗粒。通过系统地改变包括尺寸、壳厚度以及有无尖端等几何参数,我们确定了在发热过程中哪些因素最为重要。对于具有相同金含量的溶液,我们发现壳薄且有尖锐尖端的金字塔状颗粒表现出最大的光热响应。