Li Jianfeng, Noll Bruce C, Schulz Charles E, Scheidt W Robert
Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556, USA.
Angew Chem Int Ed Engl. 2009;48(27):5010-3. doi: 10.1002/anie.200901434.
Spot the difference: The five-coordinate iron(II) cyanoporphyrinates, which are spin-crossover compounds, can be used to synthesize previously unknown six-coordinate complexes. Bis(cyano) and (cyano)imidazole complexes are presented, and the five- and six-coordinate (cyano)iron(II) derivatives are compared with analogous CO complexes.
五配位氰基卟啉铁(II)是自旋交叉化合物,可用于合成此前未知的六配位配合物。文中介绍了双(氰基)和(氰基)咪唑配合物,并将五配位和六配位(氰基)铁(II)衍生物与类似的一氧化碳配合物进行了比较。