用于催化水氧化的高活性且稳定的环戊二烯基铱配合物
Highly active and robust Cp* iridium complexes for catalytic water oxidation.
作者信息
Hull Jonathan F, Balcells David, Blakemore James D, Incarvito Christopher D, Eisenstein Odile, Brudvig Gary W, Crabtree Robert H
机构信息
Chemistry Department, Yale University, P.O. Box 208107, New Haven, Connecticut 06520, USA.
出版信息
J Am Chem Soc. 2009 Jul 1;131(25):8730-1. doi: 10.1021/ja901270f.
Abstract
A series of CpIr catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a CpIr=O complex as an active species.
摘要
一系列CpIr催化剂对于用Ce(IV)进行水氧化反应而言，是目前已知活性最高的，活性超过一个数量级。密度泛函理论计算支持CpIr=O络合物作为活性物种。
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