Cady Clyde W, Crabtree Robert H, Brudvig Gary W
Department of Chemistry, Yale University, P.O. Box 208107, New Haven, CT 06520-8107, USA.
Coord Chem Rev. 2008 Feb 1;252(3-4):444-455. doi: 10.1016/j.ccr.2007.06.002.
In the last ten years, a number of advances have been made in the study of the oxygen-evolving complex (OEC) of photosystem II (PSII). Along with this new understanding of the natural system has come rapid advance in chemical models of this system. The advance of PSII model chemistry is seen most strikingly in the area of functional models where the few known systems available when this topic was last reviewed has grown into two families of model systems. In concert with this work, numerous mechanistic proposals for photosynthetic water oxidation have been proposed. Here, we review the recent efforts in functional model chemistry of the oxygen-evolving complex of photosystem II.
在过去十年中，光系统II（PSII）的析氧复合物（OEC）研究取得了多项进展。随着对自然系统的这一新认识，该系统的化学模型也迅速发展。PSII模型化学的进展在功能模型领域最为显著，上次综述该主题时仅有少数已知系统，如今已发展为两个模型系统家族。与此工作相呼应，人们提出了许多关于光合水氧化的机理假说。在此，我们综述了光系统II析氧复合物功能模型化学的最新研究成果。
