一种通过共价后合成修饰含有游离羧酸的锌基柱状桨轮金属有机框架。
A Zn-based, pillared paddlewheel MOF containing free carboxylic acids via covalent post-synthesis elaboration.
作者信息
Gadzikwa Tendai, Farha Omar K, Mulfort Karen L, Hupp Joseph T, Nguyen SonBinh T
机构信息
Department of Chemistry and the Institute for Catalysis in Energy Processes, Northwestern University, Evanston, IL 60208-3113, USA.
出版信息
Chem Commun (Camb). 2009 Jul 7(25):3720-2. doi: 10.1039/b823392f. Epub 2009 May 26.
DOI:10.1039/b823392f
PMID:19557260
Abstract
A Zn-based, mixed-ligand (pillared paddlewheel), metal-organic framework (MOF) has been covalently and quantitatively decorated with free carboxylic acids to demonstrate the utility of covalent post-synthesis modification in the construction of otherwise inaccessible carboxy-functionalized MOFs.
摘要
一种基于锌的混合配体（柱状桨轮式）金属有机框架（MOF）已通过游离羧酸进行了共价和定量修饰，以证明共价后合成修饰在构建难以通过其他方式获得的羧基官能化MOF中的实用性。
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