由化学性质稳定的位点隔离铁催化剂催化的H2O2立体选择性C-H氧化反应。 - Suppr

Stereospecific C-H oxidation with H2O2 catalyzed by a chemically robust site-isolated iron catalyst.

作者信息

Gómez Laura, Garcia-Bosch Isaac, Company Anna, Benet-Buchholz Jordi, Polo Alfonso, Sala Xavier, Ribas Xavi, Costas Miquel

机构信息

Departament de Química, Universitat de Girona, Campus de Montilivi, 17071 Girona, Spain.

出版信息

Angew Chem Int Ed Engl. 2009;48(31):5720-3. doi: 10.1002/anie.200901865.

DOI:10.1002/anie.200901865

PMID:19562811

Abstract

摘要

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引用本文的文献

Syntheses and crystal structures of (,)- and (,)-bis-(aceto-nitrile-κ)[,'-dimethyl-,'-bis(pyridin-2-ylmeth-yl)cyclo-hexane-1,2-di-amine-κ ]iron(II) bis-(hexa-fluoro-anti-monate).

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Stereospecific C-H oxidation with H2O2 catalyzed by a chemically robust site-isolated iron catalyst.

作者信息

Gómez Laura, Garcia-Bosch Isaac, Company Anna, Benet-Buchholz Jordi, Polo Alfonso, Sala Xavier, Ribas Xavi, Costas Miquel

机构信息

Departament de Química, Universitat de Girona, Campus de Montilivi, 17071 Girona, Spain.

出版信息

Angew Chem Int Ed Engl. 2009;48(31):5720-3. doi: 10.1002/anie.200901865.

DOI:10.1002/anie.200901865

PMID:19562811

Abstract

摘要

相似文献

Stereospecific C-H oxidation with H2O2 catalyzed by a chemically robust site-isolated iron catalyst.

Angew Chem Int Ed Engl. 2009;48(31):5720-3. doi: 10.1002/anie.200901865.

EDTA and electricity synergetic catalyzed Fe(3+)/H2O2 process for amoxicillin oxidation.

Water Sci Technol. 2009;60(3):761-70. doi: 10.2166/wst.2009.356.

EPR spectroscopic trapping of the active species of nonheme iron-catalyzed oxidation.

J Am Chem Soc. 2009 Aug 12;131(31):10798-9. doi: 10.1021/ja902659c.

Towards robust alkane oxidation catalysts: electronic variations in non-heme iron(ii) complexes and their effect in catalytic alkane oxidation.

Dalton Trans. 2009 Jul 21(27):5319-34. doi: 10.1039/b901390c. Epub 2009 May 19.

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J Am Chem Soc. 2009 Aug 26;131(33):11658-9. doi: 10.1021/ja903923s.

Palladium-catalyzed aromatic C-H halogenation with hydrogen halides by means of electrochemical oxidation.

J Am Chem Soc. 2009 Aug 19;131(32):11310-1. doi: 10.1021/ja9049228.

Copper-catalyzed aerobic phosphonation of sp3 C-H bonds.

Chem Commun (Camb). 2009 Jul 21(27):4124-6. doi: 10.1039/b905275e. Epub 2009 Jun 5.

Nickel-catalyzed ring-opening hydroacylation of methylenecyclopropanes: synthesis of gamma,delta-unsaturated ketones from aldehydes.

J Am Chem Soc. 2009 Aug 19;131(32):11298-9. doi: 10.1021/ja9046894.

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Inorg Chem. 2009 Sep 21;48(18):8771-83. doi: 10.1021/ic900969n.

Oxidative interception of the hydroamination pathway: a gold-catalyzed diamination of alkenes.

Chemistry. 2009 Oct 12;15(40):10563-9. doi: 10.1002/chem.200901199.

引用本文的文献

Syntheses and crystal structures of (,)- and (,)-bis-(aceto-nitrile-κ)[,'-dimethyl-,'-bis(pyridin-2-ylmeth-yl)cyclo-hexane-1,2-di-amine-κ ]iron(II) bis-(hexa-fluoro-anti-monate).

Acta Crystallogr E Crystallogr Commun. 2024 Nov 28;80(Pt 12):1350-1353. doi: 10.1107/S2056989024011307. eCollection 2024 Nov 1.

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Inorg Chem. 2024 Oct 28;63(43):20675-20688. doi: 10.1021/acs.inorgchem.4c03304. Epub 2024 Oct 18.

Highly regioselective oxidation of C-H bonds in water using hydrogen peroxide by a cytochrome P450 mimicking iron complex.

Chem Sci. 2023 Sep 8;14(38):10515-10523. doi: 10.1039/d3sc03495j. eCollection 2023 Oct 4.

Increasing the steric hindrance around the catalytic core of a self-assembled imine-based non-heme iron catalyst for C-H oxidation.

RSC Adv. 2020 Dec 24;11(1):537-542. doi: 10.1039/d0ra09677f. eCollection 2020 Dec 21.

Mechanistic Investigation of the Iron-Catalyzed Azidation of Alkyl C()-H Bonds with Zhdankin's λ-Azidoiodane.

J Am Chem Soc. 2021 Oct 6;143(39):16184-16196. doi: 10.1021/jacs.1c07330. Epub 2021 Sep 24.

Direct Photocatalyzed Hydrogen Atom Transfer (HAT) for Aliphatic C-H Bonds Elaboration.

Chem Rev. 2022 Jan 26;122(2):1875-1924. doi: 10.1021/acs.chemrev.1c00263. Epub 2021 Aug 6.

Activation of Molecular Oxygen by a Cobalt(II) Tetra-NHC Complex*.

Chemistry. 2021 Jan 18;27(4):1311-1315. doi: 10.1002/chem.202004758. Epub 2020 Dec 10.

Asymmetric Catalysis Mediated by Synthetic Peptides, Version 2.0: Expansion of Scope and Mechanisms.

Chem Rev. 2020 Oct 28;120(20):11479-11615. doi: 10.1021/acs.chemrev.0c00523. Epub 2020 Sep 24.

Syntheses of Complex Terpenes from Simple Polyprenyl Precursors.

Acc Chem Res. 2020 Apr 21;53(4):949-961. doi: 10.1021/acs.accounts.0c00055. Epub 2020 Mar 23.

O-O Bond Formation and Liberation of Dioxygen Mediated by N -Coordinate Non-Heme Iron(IV) Complexes.

Angew Chem Int Ed Engl. 2019 Sep 16;58(38):13472-13478. doi: 10.1002/anie.201903902. Epub 2019 Aug 13.

Stereospecific C-H oxidation with H2O2 catalyzed by a chemically robust site-isolated iron catalyst.

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Stereospecific C-H oxidation with H2O2 catalyzed by a chemically robust site-isolated iron catalyst.

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