基于[1,3,5]-三嗪的树枝状大分子。
Dendrimers Based on [1,3,5]-Triazines.
作者信息
Steffensen Mackay B, Hollink Emily, Kuschel Frank, Bauer Monika, Simanek Eric E
机构信息
Department of Chemistry, Texas A&M University, College Station, Texas 77843.
出版信息
J Polym Sci A Polym Chem. 2006 Jun 1;44(11):3411-3433. doi: 10.1002/pola.21333.
Abstract
A comprehensive and chronological account of dendrimers based on [1,3,5]-triazines is provided. Synthetic strategies to install the triazine through cycloaddition, cyclotrimerization, and nucleophilic aromatic substitution of cyanuric chloride are discussed. Motivations and applications of these architectures are surveyed, including the preparation of supra-molecular assemblies in the solution and solid states and their use in medicines, advanced materials, and separations when anchored to solid supports.
摘要
本文提供了基于[1,3,5]-三嗪的树枝状大分子的全面且按时间顺序排列的描述。讨论了通过环加成、环三聚化以及三聚氯氰的亲核芳香取代来安装三嗪的合成策略。对这些结构的动机和应用进行了综述，包括溶液和固态中超分子组装体的制备，以及当它们锚定在固体载体上时在药物、先进材料和分离中的应用。
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