BN 苯腈：一种缺电子的 1,2-二氢-1,2-氮杂硼烷，具有键联异构现象。
BN benzonitrile: an electron-deficient 1,2-dihydro-1,2-azaborine featuring linkage isomerism.
机构信息
Department of Chemistry, University of Oregon, Eugene, Oregon 97403, USA.
出版信息
Chem Commun (Camb). 2010 Feb 7;46(5):779-81. doi: 10.1039/b919632c. Epub 2009 Nov 25.
DOI:10.1039/b919632c
PMID:20087518
Abstract
BN Benzonitrile 2, a 1,2-dihydro-1,2-azaborine bearing an electron-withdrawing boron substituent was prepared and characterized, and its coordination chemistry investigated; reactivity studies revealed that BN benzonitrile 2 undergoes BCN-BNC linkage isomerism upon coordination to Cr(CO)(5).
摘要
BN 苯甲腈 2 是一种带有吸电子硼取代基的 1,2-二氢-1,2-氮杂硼烷，已被制备和表征，并对其配位化学进行了研究；反应性研究表明，BN 苯甲腈 2 在与 Cr(CO)(5)配位时会发生 BCN-BNC 键异构化。
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