1,2 - 二氢 - 1,2 - 氮杂硼烷对水和氧气的稳定性如何？
How stable are 1,2-dihydro-1,2-azaborines toward water and oxygen?
作者信息
Lamm Ashley N, Liu Shih-Yuan
机构信息
Department of Chemistry, University of Oregon, Eugene, Oregon 97403, USA.
出版信息
Mol Biosyst. 2009 Nov;5(11):1303-5. doi: 10.1039/b904120f. Epub 2009 Aug 10.
DOI:10.1039/b904120f
PMID:19823745
Abstract
The stability of 1,2-dihydro-1,2-azaborines toward oxygen and water was investigated as a function of their ring substituents: while generally 1,2-dihydro-1,2-azaborines are compatible with water, their stability toward oxygen is dependent on the boron and the C(3) substituents, and we found that electron withdrawing groups enhanced the heterocycle's ability to resist oxidative degradation.
摘要
研究了1,2-二氢-1,2-氮杂硼烷对氧气和水的稳定性与其环取代基的关系：虽然一般来说1,2-二氢-1,2-氮杂硼烷与水相容，但其对氧气的稳定性取决于硼和C(3)取代基，并且我们发现吸电子基团增强了杂环抵抗氧化降解的能力。
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