铑催化的环状烯烃脱氢硼化反应。
Rhodium-catalyzed dehydrogenative borylation of cyclic alkenes.
机构信息
Massachusetts Institute of Technology, Department of Chemistry, Cambridge, Massachusetts 02139, USA.
出版信息
Chem Commun (Camb). 2010 Feb 14;46(6):907-9. doi: 10.1039/b921387b. Epub 2010 Jan 5.
Abstract
A rhodium-catalyzed dehydrogenative borylation of cyclic alkenes is described. This reaction provides direct access to cyclic 1-alkenylboronic acid pinacol esters, useful intermediates in organic synthesis. Suzuki-Miyaura cross-coupling applications are also presented.
摘要
本文描述了一种铑催化的环状烯烃脱氢硼化反应。该反应为环状 1-烯基硼酸频哪醇酯提供了直接途径，这是有机合成中的有用中间体。本文还介绍了 Suzuki-Miyaura 交叉偶联反应的应用。
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本文引用的文献
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