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通讯:Johari-Goldstein 弛豫和 α 弛豫的活化势垒比较及其意义。

Communications: Comparison of activation barriers for the Johari-Goldstein and alpha relaxations and its implications.

出版信息

J Chem Phys. 2010 Jan 28;132(4):041104. doi: 10.1063/1.3306562.

Abstract

The range of activation barrier heights for the Johari-Goldstein (JG) relaxation in glasses is shown to overlap the range for the main (alpha) relaxation, but to be on the average somewhat lower. This suggests the JG relaxation, like the alpha, involve transitions between megabasins in the energy landscape, and that the original conjecture by Johari and this author that the JG relaxation is an intrabasin one cannot be correct. A further possibility is that there is a closer connection of the JG relaxation to the phenomenon of dynamic heterogeneity in supercooled liquids than so far assumed.

摘要

乔哈里-戈尔德斯坦(Johari-Goldstein,JG)弛豫的激活势垒高度范围被显示与主要(α)弛豫的范围重叠,但平均而言略低。这表明 JG 弛豫与 α 弛豫一样,涉及能量景观中巨势阱之间的跃迁,而乔哈里和作者最初提出的 JG 弛豫是势阱内跃迁的猜想不能成立。另一种可能性是,JG 弛豫与过冷液体中动态非均匀性现象的联系比目前假设的更为紧密。

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