在四丁基硼氢化铵存在下，利用黑光引发烷基碘与大气 CO 的自由基/离子羟甲基化反应。
Black-light-induced radical/ionic hydroxymethylation of alkyl iodides with atmospheric CO in the presence of tetrabutylammonium borohydride.
机构信息
Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai 599-8531, Japan.
出版信息
Org Lett. 2010 Apr 2;12(7):1548-51. doi: 10.1021/ol1002847.
PMID:20199034
Abstract
Tin-free radical/ionic hydroxymethylation of secondary and tertiary alkyl iodides proceeded efficiently in the presence of tetrabutylammonium borohydride as the hydrogen source under atmospheric pressure of CO in conjunction with photoirradiation using black light. Two possible mechanisms were proposed, both of which involve hybrid radical/ionic processes.
摘要
无锡自由基/离子羟甲基化二级和三级碘化烷基在大气压力下的 CO 存在下，以四丁基硼氢化铵作为氢源，并结合黑光光辐射，反应高效进行。提出了两种可能的机制，它们都涉及到杂化自由基/离子过程。
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