Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
Org Lett. 2010 Apr 2;12(7):1476-9. doi: 10.1021/ol1001544.
Palladium-catalyzed annulation of 1-alkynylphosphine sulfides with 2-iodoanilines followed by desulfidation affords 3-substituted 2-indolylphosphines. This annulation/desulfidation sequential protocol offers a conceptually new approach to bulky heteroarylphosphines.
钯催化 1-炔基膦硫醚与 2-碘苯胺的环化反应，随后脱硫，得到 3-取代的 2-吲哚基膦。这种环化/脱硫的顺序反应为大位阻杂芳基膦提供了一种全新的概念性方法。
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