Institut de Physique Théorique, CEA, CNRS URA 2306, F-91191 Gif sur Yvette, France.
Phys Rev Lett. 2010 Feb 12;104(6):065701. doi: 10.1103/PhysRevLett.104.065701. Epub 2010 Feb 10.
We investigate the characteristic length scales associated with the glass transition phenomenon. By studying an atomic glass-forming liquid in negatively curved space, for which the local order is well identified and the amount of frustration opposing the spatial extension of this order is tunable, we provide insight into the structural origin of the main characteristics of the dynamics leading to glass formation. We find that the structural length and the correlation length characterizing the increasing heterogeneity of the dynamics grow together as temperature decreases. However, the system eventually enters a regime in which the former saturates as a result of frustration whereas dynamic correlations keep building up.
我们研究了与玻璃转变现象相关的特征长度尺度。通过研究一种在负弯曲空间中的原子玻璃形成液体,其中局部有序性得到了很好的识别,并且阻碍这种有序性空间扩展的挫折感的量是可调的,我们深入了解了导致玻璃形成的动力学的主要特征的结构起源。我们发现,随着温度的降低,描述动力学异质性增加的结构长度和相关长度一起增长。然而,由于挫折感的作用,系统最终进入一个结构长度饱和的区域,而动态相关性仍在不断增强。