吲哚衍生卡宾的多功能配位化学。
Versatile coordination chemistry of indazole-derived carbenes.
机构信息
Department of Chemistry, National University of Singapore, 3 Science Drive 3, 117543 Singapore.
出版信息
Chem Commun (Camb). 2010 May 7;46(17):2986-8. doi: 10.1039/b925977e.
DOI:10.1039/b925977e
PMID:20376402
Abstract
The versatile coordination chemistry of strongly donating indazolin-3-ylidene ligands as new members of the NHC family is demonstrated on 12 new Pd(II), Au(I) and Rh(I) complexes, which were fully characterized by multinuclear NMR spectroscopies, ESI mass spectrometry and X-ray diffraction studies.
摘要
展示了作为 NHC 家族新成员的强给电子茚满-3-亚基配体的多功能配位化学，通过多核 NMR 光谱、ESI 质谱和 X 射线衍射研究对 12 个新的 Pd(II)、Au(I)和 Rh(I)配合物进行了全面表征。
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