连续铜催化的炔烃-叠氮化物和硫醇-烯点击反应，用于富勒烯六加成物的多功能化。
Sequential copper catalyzed alkyne-azide and thiol-ene click reactions for the multiple functionalization of fullerene hexaadducts.
机构信息
Laboratoire de Chimie des Matériaux Moléculaires, Université de Strasbourg et CNRS (UMR 7509), Ecole Européenne de Chimie, Polymères et Matériaux (ECPM), 25 rue Becquerel, 67087 Strasbourg Cedex 2, France.
出版信息
Chem Commun (Camb). 2010 Jun 21;46(23):4160-2. doi: 10.1039/c0cc00252f. Epub 2010 May 10.
PMID:20458384
Abstract
A fullerene hexakis-adduct incorporating complementary reactive centres with very different and selective reactivity has been prepared and functionalized with three different peripheral groups by successive alkyne-azide and thiol-ene click reactions.
摘要
一种富勒烯六加成物，其中包含互补的反应中心，具有非常不同和选择性的反应性，已经通过连续的炔烃-叠氮化物和硫醇-烯点击反应，用三个不同的外围基团进行了功能化。
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