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同电荷圆柱形电介质之间的反离子介导的弱耦合和强耦合静电相互作用。

Counterion-mediated weak and strong coupling electrostatic interaction between like-charged cylindrical dielectrics.

机构信息

Department of Theoretical Physics, J. Stefan Institute, SI-1000 Ljubljana, Slovenia.

出版信息

J Chem Phys. 2010 Jun 14;132(22):224703. doi: 10.1063/1.3430744.

Abstract

We examine the effective counterion-mediated electrostatic interaction between two like-charged dielectric cylinders immersed in a continuous dielectric medium containing neutralizing mobile counterions. We focus on the effects of image charges induced as a result of the dielectric mismatch between the cylindrical cores and the surrounding dielectric medium and investigate the counterion-mediated electrostatic interaction between the cylinders in both limits of weak and strong electrostatic couplings (corresponding, e.g., to systems with monovalent and multivalent counterions, respectively). The results are compared with extensive Monte Carlo simulations exhibiting good agreement with the limiting weak and strong coupling results in their respective regime of validity.

摘要

我们研究了两个带相同电荷的介电圆柱浸入含有中和移动反离子的连续介电介质中时,有效反离子介导的静电相互作用。我们关注的是圆柱核与周围介电介质之间的介电失配所产生的感应电荷的影响,并研究了在弱和强静电耦合极限下(分别对应于单价和多价反离子的系统)圆柱之间的反离子介导的静电相互作用。这些结果与广泛的蒙特卡罗模拟进行了比较,在各自的有效范围内与弱和强耦合的极限结果吻合良好。

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