SKKU Advanced Institute of Nanotechnology and Center for Human Interface Nano Technology, Sungkyunkwan University, Suwon 440-746, Korea.
Nat Nanotechnol. 2010 Aug;5(8):574-8. doi: 10.1038/nnano.2010.132. Epub 2010 Jun 20.
The outstanding electrical, mechanical and chemical properties of graphene make it attractive for applications in flexible electronics. However, efforts to make transparent conducting films from graphene have been hampered by the lack of efficient methods for the synthesis, transfer and doping of graphene at the scale and quality required for applications. Here, we report the roll-to-roll production and wet-chemical doping of predominantly monolayer 30-inch graphene films grown by chemical vapour deposition onto flexible copper substrates. The films have sheet resistances as low as approximately 125 ohms square(-1) with 97.4% optical transmittance, and exhibit the half-integer quantum Hall effect, indicating their high quality. We further use layer-by-layer stacking to fabricate a doped four-layer film and measure its sheet resistance at values as low as approximately 30 ohms square(-1) at approximately 90% transparency, which is superior to commercial transparent electrodes such as indium tin oxides. Graphene electrodes were incorporated into a fully functional touch-screen panel device capable of withstanding high strain.
石墨烯具有出色的电学、力学和化学性能,因此在柔性电子领域具有应用前景。然而,由于缺乏高效的合成、转移和掺杂石墨烯的方法,难以在应用所需的规模和质量上制备出透明导电薄膜。在此,我们报告了使用化学气相沉积法在柔性铜衬底上生长的主要为单层的 30 英寸石墨烯薄膜的卷对卷生产和湿化学掺杂。这些薄膜的方阻低至约 125 欧姆/平方,透光率高达 97.4%,并且表现出半整数量子霍尔效应,表明其质量很高。我们进一步使用层层堆叠的方法来制备掺杂的四层薄膜,并测量其在约 90%透明度下的方阻低至约 30 欧姆/平方,优于商业透明电极,如氧化铟锡。石墨烯电极被整合到一个完全功能的触摸屏面板设备中,该设备能够承受高应变。