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A hypervalent iodine-induced double annulation enables a concise synthesis of the pentacyclic core structure of the cortistatins.
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A novel α,β-unsaturated nitrone-aryne [3+2] cycloaddition and its application in the synthesis of the cortistatin core.
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Cortistatin A is a high-affinity ligand of protein kinases ROCK, CDK8, and CDK11.
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The first transannular [4+3] cycloaddition reaction: synthesis of the ABCD ring structure of cortistatins.
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Total synthesis and biological evaluation of cortistatins A and J and analogues thereof.
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