从羽毛球状的四核钴杯芳烃建筑块制备[Co24]金属大环。
Making a [Co24] metallamacrocycle from the shuttlecock-like tetranuclear cobalt-calixarene building blocks.
机构信息
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China.
出版信息
Chem Commun (Camb). 2010 Sep 14;46(34):6362-4. doi: 10.1039/c0cc01844a. Epub 2010 Aug 9.
PMID:20697642
Abstract
A [Co(24)] metallamacrocycle with a [36-MC(Co)-12] periphery and an inner [24-MC(Co)-6] rim is constructed by linking six Co(4)-thiacalixarene shuttlecock-like SBUs with twelve 1,2,4-triazole molecules.
摘要
一个具有 [36-MC(Co)-12] 外围和内部 [24-MC(Co)-6] 边缘的 [Co(24)] 金属大环通过用十二个 1,2,4-三唑分子连接六个 Co(4)-硫代杯[4] 类 SBU 构建而成。
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