通过动力学判别实现布朗斯特酸区分的金属催化。
Brønsted acid differentiated metal catalysis by kinetic discrimination.
机构信息
RWTH Aachen University, Institute of Organic Chemistry, Landoltweg 1, D-52074 Aachen, Germany.
出版信息
Chem Commun (Camb). 2011 Jan 7;47(1):304-6. doi: 10.1039/c0cc02167a. Epub 2010 Aug 17.
PMID:20717581
Abstract
A Brønsted acid differentiated metal catalyzed hydrogenation has been developed. A combinatorial variation of chiral triflylamides with achiral metal complexes results in a highly active catalyst for the asymmetric reduction.
摘要
发展了一种 Brønsted 酸区分的金属催化氢化反应。手性三氟甲酰胺与非手性金属配合物的组合变化导致了一种高效的不对称还原催化剂。
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