[Fe(F(20)TPP)Cl] 催化的分子内 C-N 键形成用于生物碱合成，使用芳基叠氮化物作为氮源。
[Fe(F(20)TPP)Cl] catalyzed intramolecular C-N bond formation for alkaloid synthesis using aryl azides as nitrogen source.
机构信息
Department of Chemistry and Open Laboratory of Chemical Biology of the Institute of Molecular Technology for Drug Discovery and Synthesis, The University of Hong Kong, Pokfulam Road, Hong Kong, China.
出版信息
Chem Commun (Camb). 2010 Oct 7;46(37):6926-8. doi: 10.1039/c0cc01825b. Epub 2010 Aug 23.
PMID:20730175
Abstract
The syntheses of alkaloids including indoles, indolines, tetrahydroquinolines, dihydroquinazolinones and quinazolinones have been accomplished in moderate to excellent yields via [Fe(F(20)TPP)Cl] catalyzed intramolecular C-N bond formation using aryl azides as nitrogen source.
摘要
通过[Fe(F(20)TPP)Cl]催化的分子内 C-N 键形成，使用芳基叠氮化物作为氮源，以中等至优异的产率完成了包括吲哚、吲哚啉、四氢喹啉、二氢喹唑啉酮和喹唑啉酮在内的生物碱的合成。
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