通过亚磺酰胺形成二硫键。
Disulfide formation via sulfenamides.
机构信息
Department of Chemistry, Washington State University, Pullman, WA 99164, USA.
出版信息
Chem Commun (Camb). 2011 Jan 7;47(1):352-4. doi: 10.1039/c0cc02076a. Epub 2010 Aug 23.
PMID:20730241
Abstract
A phosphine-mediated one-step disulfide formation from S-nitrosothiols has been developed. This reaction can convert unstable S-nitrosothiols to stable disulfides via sulfenamide intermediates under very mild conditions. It has the potential to be used for the detection of S-nitrosothiols.
摘要
研究开发了一种由亚硝酰硫醇介导的一步形成二硫键的方法。该反应可以在非常温和的条件下，通过亚磺酰胺中间体将不稳定的亚硝酰硫醇转化为稳定的二硫键。它有可能用于检测亚硝酰硫醇。
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