ARC Centre of Excellence for Functional Nanomaterials, School of Chemical Engineering, The University of New South Wales, Sydney, NSW 2052, Australia.
Nanoscale. 2010 Aug;2(8):1324-47. doi: 10.1039/c0nr00017e. Epub 2010 May 17.
Combustion of appropriate precursor sprays in a flame spray pyrolysis (FSP) process is a highly promising and versatile technique for the rapid and scalable synthesis of nanostuctural materials with engineered functionalities. The technique was initially derived from the fundamentals of the well-established vapour-fed flame aerosols reactors that was widely practised for the manufacturing of simple commodity powders such as pigmentary titania, fumed silica, alumina, and even optical fibers. In the last 10 years however, FSP knowledge and technology was developed substantially and a wide range of new and complex products have been synthesised, attracting major industries in a diverse field of applications. Key innovations in FSP reactor engineering and precursor chemistry have enabled flexible designs of nanostructured loosely-agglomerated powders and particulate films of pure or mixed oxides and even pure metals and alloys. Unique material morphologies such as core-shell structures and nanorods are possible using this essentially one step and continuous FSP process. Finally, research challenges are discussed and an outlook on the next generation of engineered combustion-made materials is given.
在火焰喷雾热解(FSP)工艺中,适当的前驱体喷雾的燃烧是一种很有前途和通用的技术,可以快速、大规模地合成具有工程功能的纳米结构材料。该技术最初源于成熟的气相火焰气溶胶反应器的基础,该反应器广泛应用于制造简单的商品粉末,如颜料钛白粉、气相法二氧化硅、氧化铝,甚至光纤。然而,在过去的 10 年中,FSP 技术得到了实质性的发展,并且合成了广泛的新型和复杂产品,吸引了不同应用领域的主要行业。FSP 反应器工程和前驱体化学方面的关键创新,使得能够灵活设计纳米结构的疏松团聚粉末和纯或混合氧化物的颗粒膜,甚至纯金属和合金。使用这种基本的一步连续 FSP 工艺,可以获得独特的材料形态,如核壳结构和纳米棒。最后,讨论了研究挑战,并展望了下一代工程燃烧制造材料。