Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
Chem Rec. 2010 Oct;10(5):348-58. doi: 10.1002/tcr.201000029.
Transition-metal-catalyzed carboborations, in which organic and boryl groups are introduced concomitantly to unsaturated organic molecules, have been developed. Direct carboborations, which proceed via activation of B-C bonds of cyanoboranes and alkynylboranes, and transmetalative carboborations, in which activation of B-Cl bonds is followed by transmetalation from organotin and organozirconium reagents, are overviewed. In addition, as representative results and mechanistic considerations, the scientific background and a personal view behind the study are also described.
发展了过渡金属催化的碳硼化反应，其中有机基团和硼基基团同时被引入到不饱和有机分子中。综述了直接碳硼化反应（通过氰基硼烷和炔基硼烷的 B-C 键的活化进行）和转金属碳硼化反应（B-Cl 键的活化后，通过有机锡和有机锆试剂的转金属化进行）。此外，作为代表性结果和机理考虑，还描述了该研究背后的科学背景和个人观点。
