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基于反应诱导电荷自电泳的电催化纳米马达的运动

Locomotion of electrocatalytic nanomotors due to reaction induced charge autoelectrophoresis.

作者信息

Moran J L, Wheat P M, Posner J D

机构信息

Mechanical Engineering and Chemical Engineering, Arizona State University, Tempe, Arizona 85287, USA.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2010 Jun;81(6 Pt 2):065302. doi: 10.1103/PhysRevE.81.065302. Epub 2010 Jun 23.

Abstract

Bimetallic rod-shaped nanomotors swim autonomously in hydrogen peroxide solutions. Here, we present a scaling analysis, computational simulations, and experimental data that show that the nanomotor locomotion is driven by fluid slip around the nanomotor surface due to electrical body forces. The body forces are generated by a coupling of charge density and electric fields induced by electrochemical reactions occurring on the nanomotor surface. We describe the dependence of nanomotor motion on the nanomotor surface potential and reaction-driven flux.

摘要

双金属棒状纳米马达在过氧化氢溶液中自主游动。在此,我们给出了标度分析、计算模拟和实验数据,这些结果表明纳米马达的运动是由纳米马达表面因电体力而产生的流体滑移驱动的。电体力是由纳米马达表面发生的电化学反应所诱导的电荷密度和电场的耦合产生的。我们描述了纳米马达运动对纳米马达表面电势和反应驱动通量的依赖性。

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