钯催化的芳炔与 2-(2-碘苯氧基)-1-取代的乙酮的环化反应。
Palladium-catalyzed annulations of arynes with 2-(2-iodophenoxy)-1-substituted ethanones.
机构信息
Key Laboratory of Chemical Biology & Traditional Chinese Medicine Research (Ministry of Education), Hunan Normal University, Changsha 410081, China.
出版信息
Chem Commun (Camb). 2010 Nov 21;46(43):8183-5. doi: 10.1039/c0cc02720k. Epub 2010 Sep 27.
PMID:20871908
Abstract
Palladium-catalyzed annulations of arynes with 2-(2-iodophenoxy)-1-substituted ethanones for the synthesis of 6H-benzo[c]chromenes are presented. This mild route allows formation of two new carbon-carbon bonds via an α-arylation/annulation process.
摘要
钯催化的芳基炔与 2-(2-碘苯氧基)-1-取代的乙酮的环加成反应，用于合成 6H-苯并[c]色烯。这种温和的路线通过α-芳基化/环加成过程形成两个新的碳-碳键。
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