Dept. Analytical Chemistry, University of Granada, Campus Fuentenueva S/N, E-18071 Granada, Spain.
Anal Chim Acta. 2010 Oct 29;679(1-2):17-30. doi: 10.1016/j.aca.2010.09.001. Epub 2010 Sep 15.
In this review, the recent evolution and the state of the art of photochemical reactions coupled with chemiluminescence processes are presented. Different chemiluminescence systems have been considered together with suitable photochemical derivatization processes that can affect either the analyte of interest or even the chemiluminogenic reagent, producing some derivatives able to participate more efficiently in the CL reactions and enhancing the CL emission. The on-line integration of the photochemical reactions as well as the coupling of this resulting photoinduced chemiluminescence (PICL) method with dynamic analytical systems, such as flow injection analysis, liquid or gas chromatography and capillary electrophoresis, have been discussed. Important applications of PICL have been proposed in environmental, pharmaceutical and food analysis.
在这篇综述中，介绍了光化学反应与化学发光过程相结合的最新进展和现状。本文考虑了不同的化学发光体系以及合适的光化学衍生化过程，这些过程可以影响感兴趣的分析物，甚至可以影响化学发光试剂，生成一些能够更有效地参与 CL 反应并增强 CL 发射的衍生物。本文还讨论了光化学反应的在线集成以及将这种光诱导化学发光（PICL）方法与流动分析系统（如流动注射分析、液相或气相色谱和毛细管电泳）相结合。PICL 在环境、药物和食品分析中的重要应用也被提出。
