Department of Chemistry, Moscow State University, Lenin Hills 1/3, 119991 Moscow, Russia.
Chem Soc Rev. 2010 Dec;39(12):5018-50. doi: 10.1039/c0cs00011f. Epub 2010 Nov 1.
The in situ MAS NMR studies of the mechanisms of zeolite catalyzed reactions are reviewed. The first part of the critical review contains brief information on the different experimental approaches used for the in situ MAS NMR studies under batch and flow conditions. In the second part, a cross reference index between the reactions studied, the catalysts used, the mechanistic information obtained and the corresponding literature sources is established. Finally, in the last part the most widely studied areas are discussed in more detail. In particular, the impact of in situ MAS NMR to unravel the mechanisms of olefin, alcohol and alkanes transformations over zeolite catalysts is analyzed (232 references).
原位 MAS NMR 研究沸石催化反应的机理综述。评论的第一部分简要介绍了在间歇和流动条件下进行原位 MAS NMR 研究的不同实验方法。第二部分建立了研究的反应、使用的催化剂、获得的机理信息和相应的文献来源之间的交叉参考索引。最后，在最后一部分详细讨论了研究最广泛的领域。特别是，分析了原位 MAS NMR 对揭示沸石催化剂上烯烃、醇和烷烃转化反应机理的影响（232 篇参考文献）。
