School of Chemistry, University of Nottingham, Nottingham, NG7 2RD, UK.
Chem Commun (Camb). 2011 Feb 14;47(6):1857-9. doi: 10.1039/c0cc04372a. Epub 2010 Dec 6.
O-Vinyl oximes were synthesised from the reaction of oximes with activated alkynes and subsequently rearranged using gold catalysis to afford highly substituted pyrroles in an efficient and regiocontrolled process. Additionally, pyrroles were formed directly from oximes and activated alkynes in a multifaceted catalysis process.
O-乙烯基肟是由肟与活化炔烃反应合成的，随后用金催化进行重排，以高效和区域控制的方式得到高度取代的吡咯。此外，吡咯也可以通过肟和活化炔烃在多相催化过程中直接形成。
