双重催化：结合光氧化还原和路易斯碱催化实现直接曼尼希反应。
Dual catalysis: combining photoredox and Lewis base catalysis for direct Mannich reactions.
机构信息
RWTH Aachen University, Institute of Organic Chemistry, Landoltweg 1, D-52074 Aachen, Germany.
出版信息
Chem Commun (Camb). 2011 Feb 28;47(8):2360-2. doi: 10.1039/c0cc04539j. Epub 2010 Dec 16.
PMID:21161098
Abstract
A dual catalytic system combining photoredox and Lewis base catalysis has been developed. By the appropriate choice of light source and catalyst, the photoredox cycle can be optimally modulated to match the base catalyzed reaction cycle to provide the corresponding products under mild reaction conditions.
摘要
已开发出一种结合光氧化还原和路易斯碱催化的双催化体系。通过适当选择光源和催化剂，可以优化光氧化还原循环以匹配碱催化反应循环，从而在温和的反应条件下提供相应的产物。
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