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Dichlorido(6-methyl-2,2'-bipyridine-κ(2)N,N')cobalt(II).

作者信息

Akbarzadeh Torbati Niloufar, Rezvani Ali Reza, Saravani Hamideh

机构信息

Department of Chemistry, University of Sistan and Baluchestan, PO Box 98135-674, Zahedan, Iran.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Nov 1;68(Pt 11):m1332. doi: 10.1107/S1600536812041116. Epub 2012 Oct 6.

Abstract

In the title compound, [CoCl(2)(C(11)H(10)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 6-methyl-2,2'-bipyridine ligand and two terminal Cl atoms. Inter-molecular C-H⋯Cl hydrogen bonds and π-π stacking inter-actions between the pyridine rings [centroid-centroid distance = 3.745 (3) Å] are present in the crystal.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ce19/3515097/5563c92742ac/e-68-m1332-fig1.jpg

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