Akbarzadeh Torbati Niloufar, Rezvani Ali Reza, Safari Nasser, Saravani Hamideh, Amani Vahid
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 18;66(Pt 10):m1284. doi: 10.1107/S1600536810036846.
In the title compound, [CoCl(2)(C(12)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 6,6'-dimethyl-2,2'-bipyridine ligand and two terminal Cl atoms. Inter-molecular C-H⋯Cl hydrogen bonds and π-π stacking inter-actions between the pyridine rings [centroid-centroid distances = 3.788 (1) and 3.957 (1) Å] are present in the crystal structure.
在标题化合物[CoCl₂(C₁₂H₁₂N₂)]中，Co(II)原子由一个6,6'-二甲基-2,2'-联吡啶配体的两个N原子和两个端基Cl原子以扭曲的四面体几何构型进行四配位。晶体结构中存在分子间C—H⋯Cl氢键以及吡啶环之间的π-π堆积相互作用[质心-质心距离 = 3.788 (1) 和3.957 (1) Å]。
Zotero 插件