二溴化{(E)-2-乙氧基-6-[3-(甲基铵基)丙基亚氨基甲基]苯酚根合}锌(II)

Zhu Xue-Wen, Yang Xu-Zhao

Key Laboratory of Surface and Interface Science of Henan, School of Materials and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, People's Republic of China.

Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 31;64(Pt 8):m1092-3. doi: 10.1107/S1600536808023672.

The title complex, [ZnBr(2)(C(13)H(20)N(2)O(2))], is a mononuclear zinc(II) compound derived from the zwitterionic form of the Schiff base (E)-2-eth-oxy-6-((3-(methyl-amino)propyl-imino)meth-yl)phenol. The Zn(II) atom is four-coordinated by the imine N and phenolate O atoms of the Schiff base ligand, and by two bromide ions, in a tetra-hedral coordination geometry. Adjacent mol-ecules are linked through inter-molecular N-H⋯O hydrogen bonds, forming chains running along the b axis.

标题配合物[ZnBr₂(C₁₃H₂₀N₂O₂)]是一种单核锌(II)化合物，由席夫碱(E)-2-乙氧基-6-((3-(甲氨基)丙基亚氨基)甲基)苯酚的两性离子形式衍生而来。Zn(II)原子通过席夫碱配体的亚胺N原子和酚盐O原子以及两个溴离子以四面体配位几何构型进行四配位。相邻分子通过分子间N-H⋯O氢键相连，形成沿b轴延伸的链。