State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, China.
Chem Commun (Camb). 2011 Mar 7;47(9):2697-9. doi: 10.1039/c0cc04644b. Epub 2011 Jan 13.
The first bimagnetic ionic liquid based on Fe and TEMPO with cooperative functionalities not only exhibited strong paramagnetic behaviour at room temperature under an applied magnetic field of 5000 Oe but also proved to be an effective catalyst for selective aerobic oxidation of aromatic alcohols under mild and clean conditions.
首例基于 Fe 和 TEMPO 的双磁性离子液体兼具协同功能,不仅在 5000Oe 外磁场下于室温表现出强顺磁行为,还可在温和清洁条件下作为有效催化剂用于芳香醇的选择性有氧氧化反应。