通过亚胺叶立德中间体的氧化还原异构化：吲哚啉和醛生成 N-烷基吲哚。
Redox isomerization via azomethine ylide intermediates: N-alkyl indoles from indolines and aldehydes.
机构信息
Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, New Jersey 08854, USA.
出版信息
Org Lett. 2011 Feb 18;13(4):812-5. doi: 10.1021/ol1031359. Epub 2011 Jan 19.
PMID:21247142
Abstract
Indolines react with aromatic and heteroaromatic aldehydes to yield N-alkyl indoles in a benzoic acid catalyzed redox isomerization reaction. Azomethine ylides are intermediates in this process which was established by intramolecular [3 + 2] trapping experiments.
摘要
吲哚啉与芳香醛和杂芳醛反应，在苯甲酸催化的氧化还原异构化反应中生成 N-烷基吲哚。亚胺叶立德是该反应的中间体，这一点通过分子内[3+2]捕获实验得到证实。
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